COMPUTER-PROGRAM FOR THE CALCULATION OF PARAMAGNETIC ENHANCEMENTS NUCLEAR-RELAXATION RATES IN SLOWLY ROTATING SYSTEMS
COMPUTER-PROGRAM FOR THE CALCULATION OF PARAMAGNETIC ENHANCEMENTS NUCLEAR-RELAXATION RATES IN SLOWLY ROTATING SYSTEMS
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DOI：
10.1006/jmra.1995.1074
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发表时间：
1995-04-01
期刊：
影响因子：
--
通讯作者：
PARIGI, G
中科院分区：
文献类型：
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作者：
BERTINI, I;GALAS, O;PARIGI, G
本文编制了一个计算机程序，用于计算当Solomon-Bloembergen方程失效时，慢旋转系统中核弛豫率随磁场的顺磁增强。在静态自旋哈密顿参数中包含的g各向异性、零场分裂和与金属核的超精细耦合提供了对电子自旋系统的描述，这对大多数实验情况来说实际上是完整和足够的。所有三个张量项都可以包含菱形分量，并且它们可以同时处理，只要张量共享相同的主轴。(C)出版社：Academic Press
A computer program has been developed for the calculation of paramagnetic enhancement of nuclear-relaxation rates as a function of magnetic field in slowly rotating systems, when the Solomon-Bloembergen equations break down. The inclusion in the static spin-Hamiltonian parameters of g anisotropy, zero-field splitting, and hyperfine coupling with the metal nucleus provides a description of the electron spin system which is practically complete and adequate for most experimental cases, All three tensorial terms may include rhombic components and they can be treated simultaneously, provided that the tensors share the same principal axes. (C) 1995 Academic Press, Inc.