Coordination chemistry of poly(thioether)borate ligands.

Coordination chemistry of poly(thioether)borate ligands.
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DOI:
10.1016/j.ccr.2010.01.007
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发表时间:
2010-08-01
影响因子:
20.6
通讯作者:
Riordan CG
Riordan CG
中科院分区:
化学1区
文献类型:
--
作者:
Riordan CG

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This review traces the development and application of the tris(thioether)borate ligands, tripodal ligands with highly polarizable thioether donors. Areas of emphasis include the basic coordination chemistry of the mid-to-late first row transition metals (Fe, Ni, Co, Cu), and the role of the thioether substituent in directing complex formation, the modeling of zinc thiolate protein active sites, high-spin organo-iron and organo-cobalt chemistry, the preparation of monovalent complexes of Fe, Co and Ni, and dioxygen and sulfur activation by monovalent nickel complexes.
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