Coordination chemistry of poly(thioether)borate ligands.
Coordination chemistry of poly(thioether)borate ligands.
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DOI:
10.1016/j.ccr.2010.01.007
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发表时间:
2010-08-01
影响因子:
20.6
通讯作者:
Riordan CG
中科院分区:
文献类型:
--
作者:
Riordan CG
This review traces the development and application of the tris(thioether)borate ligands, tripodal ligands with highly polarizable thioether donors. Areas of emphasis include the basic coordination chemistry of the mid-to-late first row transition metals (Fe, Ni, Co, Cu), and the role of the thioether substituent in directing complex formation, the modeling of zinc thiolate protein active sites, high-spin organo-iron and organo-cobalt chemistry, the preparation of monovalent complexes of Fe, Co and Ni, and dioxygen and sulfur activation by monovalent nickel complexes.
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通讯作者:
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