Electrocatalytic hydrogenation of nitriles: A step toward electrification of amine production
Electrocatalytic hydrogenation of nitriles: A step toward electrification of amine production
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DOI：
10.1016/j.checat.2021.06.003
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发表时间：
2021-07
期刊：
影响因子：
--
通讯作者：
Ricardo Mathison;M. Modestino
中科院分区：
文献类型：
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作者：
Ricardo Mathison;M. Modestino
在本期《化学催化》中，Zhang 等人。描述了一种在纳米结构铜电催化剂上将腈电化学氢化为伯胺的方法。通过使用二氧化碳饱和电解质，伯胺可逆地转化为氨基甲酸或氨基甲酸酯，从而防止它们缩合成仲胺或叔胺。
In this issue ofChem Catalysis, Zhang et al. describe a method to electrochemically hydrogenate nitriles to primary amines on nanostructured copper electrocatalysts. Through the implementation of CO2-saturated electrolytes, the primary amines are reversibly converted to carbamic acids or carbamates, which prevents their condensation into secondary or tertiary amines.