Electrocatalytic Aziridination of Alkenes Mediated by n-Bu4NI: A Radical Pathway
Electrocatalytic Aziridination of Alkenes Mediated by n-Bu4NI: A Radical Pathway
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n-Bu4NI 介导的烯烃电催化氮丙啶化：一种自由基途径
DOI：
10.1021/acs.orglett.5b00083
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发表时间：
2015-02-20
期刊：
影响因子：
5.2
通讯作者：
Little, R. Daniel
中科院分区：
文献类型：
--
作者：
Chen, Jie;Yan, Wei-Qing;Little, R. Daniel
首次实现了烯烃的高效电催化氮丙啶化反应。一个结构广泛的氮杂环丙烷很容易访问使用未分割的细胞在恒定电流下运行，并介导的催化量的n-Bu 4 NI。电催化反应也在没有额外的导电盐的情况下进行。该反应遵循自由基反应机理。
Efficient electrocatalytic aziridination of alkenes has been achieved for the first time. A structurally broad range of aziridines was easily accessed using an undivided cell operated at constant current and mediated by a catalytic quantity of n-Bu4NI. The electrocatalytic reaction also proceeded in the absence of additional conducting salt. The aziridination is proposed to follow a radical mechanism.