Indium-free multilayer semi-transparent electrodes for polymer solar cells
Indium-free multilayer semi-transparent electrodes for polymer solar cells
复制标题
DOI：
10.1016/j.solmat.2015.10.010
复制
发表时间：
2016-01-01
影响因子：
6.9
通讯作者：
Lidzey, David G.
中科院分区：
文献类型：
--
作者：
Barrows, Alexander T.;Masters, Rob;Lidzey, David G.
我们探索了用于 PCDTBT:PC70BM 有机光伏 (OPV) 器件的无铟电极的制造，并比较了作为器件阳极的不同多层电极。研究了由 MoO3/Ag/MoO3 (MAM) 和 TeO2/Ag/MoO3 (TAM) 多层组成的两种氧化物/金属/氧化物结构。通过扫描电子显微镜测量，我们发现，与 MoO3 种子层相比，使用 TeO2 种子层的电极促进了更连续的银层以较低的膜厚度生长，从而将增强的光透射率（约 7%）与低薄层电阻（14 Ω/平方）结合在一起。这种增强的光学透射率导致光伏电池的短路电流增加，基于 TAM 的器件的功率转换效率比使用类似的 MAM 电极制造的器件高出约 6%。 (C) 2015 年作者。由 Elsevier B.V 出版。这是一篇基于 CC BY 许可证 (http://creativecommons.org/licenses/by/4.0/) 的开放获取文章。
We have explored the fabrication of indium-free electrodes for use in a PCDTBT:PC70BM organic photovoltaic (OPV) device, and compare different multilayer electrodes as the device anode. Two oxide/metal/oxide structures were investigated that consisted of MoO3/Ag/MoO3 (MAM) and TeO2/Ag/MoO3 (TAM) multilayers. Using scanning electron microscopy measurements, we find that the electrode utilising a TeO2 seed layer encouraged the growth of a more continuous silver layer at low film thickness relative to an MoO3 seed layer, and thus combines enhanced optical transmission (by around 7%) with low sheet resistance (14 Omega/square). This enhanced optical transmittance results in an increased short-circuit current in photovoltaic cells, with TAM-based devices having a power conversion efficiency around 6% higher than those fabricated using a comparable MAM electrode. (C) 2015 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).