Enantioselective aldol reactions of trichlorosilyl enol ethers catalyzed by the chiral phosphine oxide BINAPO
Enantioselective aldol reactions of trichlorosilyl enol ethers catalyzed by the chiral phosphine oxide BINAPO
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DOI：
10.1055/s-2006-939725
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发表时间：
2006-05-03
期刊：
影响因子：
2
通讯作者：
Nakajima, Makoto
中科院分区：
文献类型：
--
作者：
Kotani, Shunsuke;Hashimoto, Shunichi;Nakajima, Makoto
手性氧化膦BINAPO催化醛与三氯硅烯醇醚的不对称羟醛缩合反应，得到了高对映选择性和高对映选择性的羟醛加成物.
The enantioselective aldol reactions of aldehydes with trichlorosilyl enol ethers catalyzed by chiral phosphine oxide BINAPO afforded the corresponding aldol adducts with high diastereo- and enantioselectivities.