Rhodium-Catalyzed Arylzincation of Terminal Allenes Providing Allylzinc Reagents and Its Application to Versatile Three-component Coupling Reaction
Rhodium-Catalyzed Arylzincation of Terminal Allenes Providing Allylzinc Reagents and Its Application to Versatile Three-component Coupling Reaction
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DOI：
10.1021/ja102303s
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发表时间：
2010-07-07
影响因子：
15
通讯作者：
Oshima, Koichiro
中科院分区：
文献类型：
--
作者：
Yoshida, Yuji;Murakami, Kei;Oshima, Koichiro
铑催化末端烯基的区域选择性芳基锌化提供了合成上有用的功能化烯基锌试剂。烯丙基锌试剂与多种亲电试剂反应，如乙唑，提供更通用的三组分偶联反应。
Rhodium-catalyzed regioselective arylzincation of terminal allenes affords synthetically useful functionalized allylzinc reagents. The allylzinc reagents react with a variety of electrophiles such as acetomtnle, offering a more versatile three-component coupling reaction.