Radical pairs with rotational fluidity in the photochemical reaction of acetophenone and cyclohexane in the zeolite NAY: a (13)C CPMAS NMR and product analysis study.
Radical pairs with rotational fluidity in the photochemical reaction of acetophenone and cyclohexane in the zeolite NAY: a (13)C CPMAS NMR and product analysis study.
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苯乙酮和环己烷在沸石 NAY 中的光化学反应中具有旋转流动性的自由基对：(13)C CPMAS NMR 和产物分析研究。
DOI：
10.1039/b815266g
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发表时间：
2009
影响因子：
3.2
通讯作者：
GarciaGaribay,MiguelA
中科院分区：
文献类型：
--
作者：
Amboya,Ammee;Nguyen,Tina;Huynh,THien;Brown,Ashley;Ratliff,Gretchen;Yonutas,Heather;Cizmeciyan,Deniz;Natarajan,Arunkumar;GarciaGaribay,MiguelA
苯乙酮和环己烷在沸石NaY中的光化学反应发生由成对的自由基对的组合，得到的产品，揭示了显着的量的旋转流动性，这也被记录的分子间核偶极相互作用测量使用交叉极化13 C NMR（CPMAS）实验。
The photochemical reaction of acetophenone and cyclohexane in the zeolite NaY occurs by combination of the geminate radical pairs to give products that reveal a significant amount of rotational fluidity, which was also documented by intermolecular nuclear dipolar interaction measurements using cross polarization 13C NMR (CPMAS) experiments.