Alkali-metal bis(aryl)formamidinates: a study of coordinative versatility
Alkali-metal bis(aryl)formamidinates: a study of coordinative versatility
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DOI：
10.1039/b613984a
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发表时间：
2007-04-28
影响因子：
4.9
通讯作者：
Cole, Marcus L.
中科院分区：
文献类型：
--
作者：
Junk, Peter C.;Cole, Marcus L.
碱金属脒基试剂，特别是甲脒基试剂的开发与过渡金属键合（例如金属-金属键合）的基本进展以及早期过渡金属催化中逐渐脱离非金属载体配体的进展齐头并进。这个高度个性化的帐户突出了一个碱金属脒亚类的配位多功能性;双（芳基）甲脒。这些化合物在过渡金属研究中被证明是非常宝贵的，但在我们的工作之前，它们本身被认为不值得研究。
The development of alkali-metal amidinate reagents, in particular formamidinates, has proceeded hand-in-hand with fundamental advances in transition-metal bonding, e.g. metal-metal bonding, and the progressive departure from cyclopentadienyl support ligands in early transition-metal catalysis. This highly personalised account highlights the coordinative versatility of one alkali-metal amidinate subclass; the bis(aryl)formamidinates. These compounds have proven invaluable during transition-metal studies but were considered unworthy of investigation in their own right prior to our work.