Polymerization of N-vinylcarbazole by gaseous initiators
Polymerization of N-vinylcarbazole by gaseous initiators
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DOI：
10.1002/app.1992.070440119
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发表时间：
1992-01
影响因子：
3
通讯作者：
S. N. Bhadani;S. Gupta;A. K. Sinha
中科院分区：
文献类型：
--
作者：
S. N. Bhadani;S. Gupta;A. K. Sinha
本文研究了以NO_2和SO_2为引发剂的N-乙烯基咔唑在二氯乙烷中的聚合反应。聚合动力学用重量分析法跟踪。用NO2聚合快，但用SO2获得相对慢的速率。这些气体的聚合似乎是由电荷转移机制引发的。
The polymerization of N-vinylcarbazole initiated with NO2 and SO2 in dichloroethane has been studied. The kinetics of polymerization were followed gravimetrically. The Polymerization is fast with NO2 but a relatively slow rate was obtained with SO2. The polymerization with these gases appears to be initiated by a charge transfer mechanism.