NONLINEAR EFFECTS IN ASYMMETRIC CATALYSIS
NONLINEAR EFFECTS IN ASYMMETRIC CATALYSIS
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DOI：
10.1021/ja00100a004
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发表时间：
1994-10-19
影响因子：
15
通讯作者：
KAGAN, HB
中科院分区：
文献类型：
--
作者：
GUILLANEUX, D;ZHAO, SH;KAGAN, HB
在涉及部分拆分配体的不对称催化反应中，可能会出现一些看似不寻常的现象。偏离线性（之间的ee的配体和ee的产品）是可能的，并考虑使用简化模型的各种情况。的基本特征突出的模型考虑到非对映体协会内（模型1）或外（模型2）的催化循环。实验发现的各种情况下被认为是。
Seemingly unusual phenomena may occur in asymmetric catalysis involving partially resolved ligands. Deviations from linearity (between the ee of the ligand and the ee of the product) are possible, and various cases are considered using simplified models. The fundamental features are highlighted in models taking into account diastereomeric associations inside (model 1) or outside (model 2) the catalytic cycle. Various cases found experimentally are considered.