Iron-Mediated Cleavage of C-C Bonds in Vicinal Tricarbonyl Compounds in Water
Iron-Mediated Cleavage of C-C Bonds in Vicinal Tricarbonyl Compounds in Water
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DOI：
10.1002/anie.200806296
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发表时间：
2009-01-01
影响因子：
16.6
通讯作者：
Schofield, Christopher J.
中科院分区：
文献类型：
--
作者：
Mecinovic, Jasmin;Hamed, Refaat B.;Schofield, Christopher J.
三种：邻位三羰基化合物在铁离子的作用下发生C → C断裂（见示意图）。观察到的茚三酮和脱氢抗坏血酸的裂解与氨基酸检测和维生素C代谢相关。
Three of a kind: Vicinal tricarbonyl compounds undergo CC cleavage mediated by ferric ions (see scheme). The observed cleavage of ninhydrin and dehydroascorbic acid has relevance for amino acid detection and the metabolism of vitamin C.