Stoicheiometric hydrogenation of olefins using HRuCl(PPh3)3 and formation of an ortho-metallated ruthenium(II) complex

Stoicheiometric hydrogenation of olefins using HRuCl(PPh3)3 and formation of an ortho-metallated ruthenium(II) complex
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使用 HRuCl(PPh3)3 对烯烃进行化学计量氢化并形成邻位金属化钌 (II) 络合物

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发表时间:
1974
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通讯作者:
Daniel K. W. Wang
Daniel K. W. Wang
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作者:
B. James;L. D. Markham;Daniel K. W. Wang

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在无氢的条件下,用HRuCl(PPh3)3对烯烃进行化学计量加氢反应生成二聚体[(Ph3p)ClRu(o-C6H4PPh2)]2;该络合物在溶液中与H2和HCl反应,生成具有催化意义的双膦配合物RuXCl(PPh3)2(X=H,Cl)。
Stoicheiometric hydrogenation of olefins using HRuCl(PPh3)3 in the absence of hydrogen results in formation of the dimer [(Ph3P)ClRu(o-C6H4PPh2)]2; this complex reacts with H2, and HCl, to yield in solution the catalytically important bisphosphine complexes RuXCl(PPh3)2(X = H, Cl).