Hypervalent organobismuth complexes: pathways toward improved reactivity, catalysis, and applications
Hypervalent organobismuth complexes: pathways toward improved reactivity, catalysis, and applications
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高价有机铋配合物：改善反应性、催化作用和应用的途径
DOI：
10.1039/d3dt02313c
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发表时间：
2023
影响因子：
4
通讯作者：
Hyvl, Jakub
中科院分区：
文献类型：
--
作者：
Hyvl, Jakub
有机双金属配合物中的超价（三中心，四电子）键由于其影响分子几何形状，动力学行为或稳定配体支架的能力而被广泛研究。这项工作解决了这种键合的反应性，催化活性，氧化还原过程的影响，其在生物科学，材料科学和小分子活化的潜在应用。
Hypervalent (three-center, four-electron) bonding in organobismuth complexes has been extensively studied due to its ability to affect molecular geometry, dynamic behavior, or to stabilize the ligand scaffold. This work addresses the effects of this bonding on reactivity, catalytic activity, redox processes, and its potential applications in biosciences, materials science, and small molecule activation.