High yield thiolation of iodobenzene catalyzed by the phosphinite nickel PCP pincer complex: [NiCl{C6H3-2,6-(OPPh2)2}]

High yield thiolation of iodobenzene catalyzed by the phosphinite nickel PCP pincer complex: [NiCl{C6H3-2,6-(OPPh2)2}]
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DOI:
10.1016/j.tetlet.2006.05.094
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发表时间:
2006-07-17
影响因子:
1.8
通讯作者:
Morales-Morales, David
Morales-Morales, David
中科院分区:
化学4区
文献类型:
--
作者:
Gomez-Benitez, Valente;Baldovino-Pantaleon, Oscar;Morales-Morales, David

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NiCl(C_6H_3 - 2,6-(OPPh_2)(2))]有效地催化碘代苯在锌存在下与宽范围的二硫化物的硫醇化反应,偶联产物以优异的产率获得,在许多情况下几乎是定量的产率。(c)2006爱思唯尔有限公司保留所有权利。
NiCl (C6H3-2,6-(OPPh2)(2))] efficiently catalyzes the thiolation of iodobenzene with a broad scope of disulfides in the presence of zinc, the coupled products are obtained in excellent and in many cases nearly quantitative yields. (c) 2006 Elsevier Ltd. All rights reserved.