ADMET: The Future Revealed

ADMET: The Future Revealed
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DOI:
10.1021/ma400067b
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发表时间:
2013-06-25
期刊:
影响因子:
5.5
通讯作者:
Schulz, Michael D.
Schulz, Michael D.
中科院分区:
化学1区
文献类型:
--
作者:
Atallah, Pascale;Wagener, Kenneth B.;Schulz, Michael D.

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烯烃复分解已被聚合物化学家所接受,作为一种创造定义良好的聚合物的方法。特别是,ADMET和ROMP已经成为复分解聚合的主要模式。ADMET反应现在很常见,可以在教科书中找到,如果选择适当的技术,很容易进行。然而,还有很多工作要做,现在的工作重点是硅化学,精密聚合物的直接控制,生物应用,普通聚烯烃的晶格建模,探索固态复分解反应,以及创造水溶性ADMET聚合物。
Olefin metathesis has been embraced by polymer chemists as a method for creating well-defined polymers. In particular, ADMET and ROMP have emerged as the primary modes of metathesis polymerization. ADMET reactions are now common, found in textbooks, and easy to perform if the proper techniques are chosen. Much remains to be done, however, with work now focusing on silicon chemistry, direct control of tacticity in precision polymers, biological applications, modeling crystal lattices in common polyolefins, exploring solid-state metathesis reactions, and creating water-soluble ADMET polymers.