Graphite Intercalation Compounds. II. Transport and Electronic Properties
Graphite Intercalation Compounds. II. Transport and Electronic Properties
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石墨插层化合物。
DOI：
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发表时间：
1995
期刊：
影响因子：
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通讯作者：
E. Gey
中科院分区：
文献类型：
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作者：
E. Gey
概述了用于计算团簇最稳定结构及其性质的量子力学模型，例如团簇中不同类型的键合或相变。讨论了簇的幻数以及壳结构和超壳结构的存在性。从实用的角度来看，重要的是解释小团簇性质的大小依赖关系，如结合能或电离能、比电阻、可压缩性、熔化温度或表面自由能，并为计算这些依赖关系提供解析表达式。统计理论报道了激发态团簇的解离。本书的一部分介绍了实验方法，以产生大小选择集群和检测它们。据报道，对元素周期表中不同元素形成的团簇进行了广泛的研究，涵盖从碱金属团簇到稀有气体团簇的范围。讨论了碱金属中氧化物和卤化物团簇的结果，以及中性分子团簇的结果。当然有一章是讲碳团簇和富勒烯的。考虑到这些广泛的主题，作者的目的是写一本教科书
provide an overview about quantum mechanical models for calculating the most stable configurations of clusters and their properties as e.g. different types of bonding or phase transitions in clusters. Magic numbers of constituents of the clusters as well as the existence of shell structures and supershells are discussed. Important especially from the practical point of view is the explanation of the size dependence of the properties of small clusters like binding or ionization energies, specific electrical resistance, compressibility, melting temperatures or surface free energies and to make analytical expressions available for the calculation of these dependences. Statistical theories are reported for the dissociation of excited clusters. A part of the book introduces in the experimental methods to produce size selected clusters and to detect them. Extensive studies on clusters formed by different elements of the periodic table are reported covering the range from alkali metal clusters to the clusters of rare gases. Results on clusters of oxides and halides of alkali metals are discussed as well as results of clusters formed of neutral molecules. Of course one finds a chapter dealing with carbon clusters and fullerenes. Looking on this broad variety of subjects the aim of the authors to write a text book