Functional metal-bipyridinium frameworks: self-assembly and applications.
Functional metal-bipyridinium frameworks: self-assembly and applications.
复制标题
DOI：
10.1039/c5dt03195h
复制
发表时间：
2015-11
影响因子：
4
通讯作者：
Jian-Ke Sun;Jie Zhang
中科院分区：
文献类型：
--
作者：
Jian-Ke Sun;Jie Zhang
金属有机骨架材料作为一种新兴材料，近年来得到了迅速的发展。模块化合成程序允许将官能团整合到具有不同应用的框架中。由于骨架的容易修饰和具有有趣的电子活性的高电荷特性，使用联吡啶衍生物作为用于制造功能性金属-联吡啶框架（MBPF）的配体在过去几年中引起了越来越多的兴趣。各种含联吡啶的配体被设计用于构建功能性MBPF，其中一些具有有趣的性质，具有潜在的应用前景，包括光致变色和光开关、传感、分子吸附和分离。这一观点旨在突出这一领域的最新进展，并寻求发现有希望的想法，这些想法将强调未来在基础和应用层面的进步。
Metal-organic frameworks (MOFs) as newly emerged materials have experienced rapid development in the last few years. The modular synthesis procedure allows integrating functional groups in their frameworks with varied applications. Due to the easy modification of the backbone and highly charged characteristics with interesting electron-active properties, the use of bipyridinium derivatives as synthons for the fabrication of functional metal-bipyridinium frameworks (MBPFs) has attracted increased interest over the past few years. Various bipyridinium-bearing ligands have been designed for the construction of functional MBPFs, and some of them present intriguing properties for potential applications including photochromism and photoswitching, sensing, molecule adsorption and separation. This perspective aims to highlight the recent progress in this area, and seeks to uncover promising ideas that will underscore future advancements at both the fundamental and applied levels.