A two-dimensional zeolitic imidazolate framework with a cushion-shaped cavity for CO2 adsorption
A two-dimensional zeolitic imidazolate framework with a cushion-shaped cavity for CO2 adsorption
复制标题
用于CO2吸附的具有垫形空腔的二维沸石咪唑酯骨架
DOI：
10.1039/c3cc44342f
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发表时间：
2013-01-01
影响因子：
4.9
通讯作者：
Wang, Huanting
中科院分区：
文献类型：
--
作者：
Chen, Rizhi;Yao, Jianfeng;Wang, Huanting
在室温下，在锌盐和2 - 甲基咪唑（Hmim）水溶液中合成了一种新的二维沸石咪唑酯骨架结构（命名为ZIF - L）。ZIF - L（Zn(mim)₂·(Hmim)½·(H₂O)³/₂或C₁₀H₁₆N₅O₃/₂Zn）具有独特的垫状空腔和叶状晶体形态，并表现出优异的二氧化碳吸附性能。
A new two-dimensional zeolitic imidazolate framework (named as ZIF-L) was synthesized in zinc salt and 2-methylimidazole (Hmim) aqueous solution at room temperature. ZIF-L (Zn(mim)(2)center dot(Hmim)(1/2)center dot(H2O)(3/2) or C10H16N5O3/2Zn) has unique cushion-shaped cavities and leaf-like crystalmorphology, and exhibits excellent CO2 adsorption properties.