Synthesis of Unsymmetrically Substituted 2,2' -Dihydroxy-1,1'-biaryl Derivatives Using Organic-Base-Catalyzed Ferrier-Type Rearrangement as the Key Step
Synthesis of Unsymmetrically Substituted 2,2' -Dihydroxy-1,1'-biaryl Derivatives Using Organic-Base-Catalyzed Ferrier-Type Rearrangement as the Key Step
复制标题
以有机碱催化的费耶型重排为关键步骤合成不对称取代的2,2-二羟基-1,1-联芳衍生物
DOI：
10.1039/c2cc31594g
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发表时间：
2012
期刊：
影响因子：
--
通讯作者：
K. Dan
中科院分区：
文献类型：
--
作者：
M. Terada;K. Dan
A strong organic base, TBD, functioned as a unique catalyst for the intramolecular multi-step transformation of lactols using the Ferrier-type rearrangement as the key step to provide unsymmetrically substituted 2,2′-dihydroxy biaryl compounds having four ortho substituents about the biaryl axis without the need for a metal catalyst.
