Molecular protection of fatty acid methyl esters within a supramolecular capsule

Molecular protection of fatty acid methyl esters within a supramolecular capsule
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DOI:
10.1039/c9cc06501f
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发表时间:
2019-10-07
影响因子:
4.9
通讯作者:
Gibb, Bruce C.
Gibb, Bruce C.
中科院分区:
化学2区
文献类型:
--
作者:
Wang, Kaiya;Jordan, Jacobs H.;Gibb, Bruce C.

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我们描述了使用超分子纳米胶囊选择性保护顺式和反式c18单不饱和脂肪酸酯。与早期的研究相反,揭示小酯的保护是由亲和力决定的,这些大酯的保护被发现依赖于客体的包装基序。
We describe the use of a supramolecular nano-capsule for selective protection of cis- and trans-C18 mono-unsaturated fatty-acid esters. In contrast to earlier studies revealing that protection of smaller esters is dictated by affinity, protection of these larger esters was found to be dependent on the packing motif of the guest.