Synthesis of primary amines by the electrophilic amination of Grignard reagents with 1,3-dioxolan-2-one O-sulfonyloxime
Synthesis of primary amines by the electrophilic amination of Grignard reagents with 1,3-dioxolan-2-one O-sulfonyloxime
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DOI：
10.1021/ol0479951
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发表时间：
2004-11-25
期刊：
影响因子：
5.2
通讯作者：
Narasaka, K
中科院分区：
文献类型：
--
作者：
Kitamura, M;Suga, T;Narasaka, K
[图]伯胺是由格氏试剂与4,4,5,5-四甲基-1,3-二恶唑-2- 1 -o -苯基磺酰肟的亲电胺化反应和生成的亚胺的酸性水解制备的。
[GRAPHICS]Primary amines are prepared by the electrophilic amination of Grignard reagents with 4,4,5,5-tetramethyl-1,3-dioxolan-2-one O-phenyisulfonyloxime and the acidic hydrolysis of the resulting imines.