Analysis of polymer materials by surface NMR via the MOUSE

Analysis of polymer materials by surface NMR via the MOUSE
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DOI:
10.1006/jmre.1997.1282
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发表时间:
1998-01-01
影响因子:
2.2
通讯作者:
Blümich, B
Blümich, B
中科院分区:
化学3区
文献类型:
--
作者:
Guthausen, A;Zimmer, G;Blümich, B

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讨论了一种新型核磁共振设备,核磁共振鼠标(移动通用表面探测器),用于表征聚合物。弹性体的不同性能与有效的横向松弛参数T-2eff有关。多回波序列影响衰减曲线,可以用B-0不均匀性和自旋锁效应来描述。此外,在非均匀磁场条件下,通过对稳态自由进动(SSFP)脉冲序列进行改进,可以提高信号的信噪比。(C) 1998学术出版社。
Applications are discussed of a novel NMR device, the NMR MOUSE (mobile universal surface explorer), for characterization of polymers. Different properties of elastomers can be related to an effective transverse relaxation parameter T-2eff. Effects of multiecho sequences influence the decay curve and can be described in terms of B-0 inhomogeneity and spin-lock effects. Furthermore, the signal-to-noise ratio (SIN) can be improved by use of steady-state free precession (SSFP) pulse sequences modified for use in inhomogeneous magnetic fields. (C) 1998 Academic Press.