Novel monodentate spiro phosphorus ligands for rhodium-catalyzed hydrogenation reactions
Novel monodentate spiro phosphorus ligands for rhodium-catalyzed hydrogenation reactions
复制标题
DOI：
10.1039/b109827f
复制
发表时间：
2002-01-01
影响因子：
4.9
通讯作者：
Zhou, QL
中科院分区：
文献类型：
--
作者：
Fu, Y;Xie, JH;Zhou, QL
含有 1,1 螺二茚满骨架的新型单齿磷配体已被合成并应用于官能化烯烃的不对称铑催化氢化，提供优异的对映选择性（高达 99.3% ee）。
Novel monodentate phosphorus ligands containing the 1,1 spirobiindane backbone have been synthesized and applied in the asymmetric rhodium-catalyzed hydrogenation of functionalized olefins, providing excellent enantioselectivities (up to 99.3% ee).