Nitrogen dioxide adsorption on deuteroxylated titania (anatase)

Nitrogen dioxide adsorption on deuteroxylated titania (anatase)
复制标题

DOI：
10.1039/ft9928803087
复制
发表时间：
1993-01
期刊：
Journal of the Chemical Society, Faraday Transactions
影响因子：
--
通讯作者：
M. Kantcheva;V. Bushev;K. Hadjiivanov
M. Kantcheva;V. Bushev;K. Hadjiivanov
中科院分区：
其他
文献类型：
--
作者：
M. Kantcheva;V. Bushev;K. Hadjiivanov

文献摘要

被引文献

相似文献

用红外光谱法研究了锐钛矿和脱氧TiO2对No2的吸附。结果表明，NO2与锐钛矿表面羟基（deuteroxyl）反应生成硝酸盐和水分子（H2O、HOD和D2O）弱键，而在表面Lewis酸碱对位点上，NO2歧化生成NO+和硝酸盐。研究了不同吸附形式的稳定性，并讨论了它们的结构。
The adsorption of No2 on anatase and deuteroxylated TiO2 is investigated by IR spectroscopy. It is established that NO2 reacts with the surface hydroxyl (deuteroxyl) groups of anatase to give nitrates and water molecules (H2O, HOD and D2O) weakly bonded to the nitrates, while on the surface Lewis acidic–basic pairs of sites, NO2 disproportionates to NO+ and nitrates. The stability of the different adsorption forms is studied and their structures are discussed.