One-step heterogeneous assembly of terbium(iii) and silver(i) with thiacalix[4]arene ligands to form a cage including terbium(iii) in an octa-oxygen cube
One-step heterogeneous assembly of terbium(iii) and silver(i) with thiacalix[4]arene ligands to form a cage including terbium(iii) in an octa-oxygen cube
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铽(iii)和银(i)与硫杂[4]芳烃配体的一步异质组装，形成八氧立方体中包含铽(iii)的笼
DOI：
10.1007/s10847-009-9567-0
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发表时间：
2009
影响因子：
2.3
通讯作者：
H. Hoshino
中科院分区：
文献类型：
--
作者：
Teppei Tanaka;Nobuhiko Iki;T. Kajiwara;M. Yamashita;H. Hoshino
Ag+、Tb 3+和硫杂杯[4]芳烃（TCAS）的非均相一步自组装得到了一个超分子笼状化合物$$ {\text{Ag}}_{4}^{ + } \cdot{\text{Tb}}^{ 3+ } \cdot {\text{TCAS}}_{ 2} $$，在其中心处，八氧立方体包封Tb 3+中心以将其与溶剂分子完全屏蔽。
A heterogeneous one-step self-assembly of Ag+, Tb3+, and thiacalix[4]arene (TCAS), of which the donor atoms S and O showed high selectivity toward Ag+ and Tb3+ ions, respectively, afforded a supramolecular cage compound, $$ {\text{Ag}}_{4}^{ + } \cdot{\text{Tb}}^{ 3+ } \cdot{\text{TCAS}}_{ 2} $$, at the center of which an octa-oxygen cube encapsulated the Tb3+ center to completely shield it from solvent molecules.