Palladium/Norbornene Cooperative Catalysis.
Palladium/Norbornene Cooperative Catalysis.
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DOI：
10.1021/acs.chemrev.9b00079
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发表时间：
2019-04
期刊：
影响因子：
62.1
通讯作者：
Jianchun Wang;Guangbin Dong
中科院分区：
文献类型：
--
作者：
Jianchun Wang;Guangbin Dong
钯/降冰片烯协同催化已成为一种从容易获得的起始材料构建多官能化芳烃的独特方法。本综述对该领域进行了全面的概述，包括早期的化学计量研究、催化反应的发展以及在生物活性化合物和聚合物合成中的应用。催化反应部分根据反应引发方式分为两部分：Pd(0)引发反应和Pd(II)引发反应。
Palladium/norbornene cooperative catalysis has emerged as a distinct approach to construct polyfunctionalized arenes from readily available starting materials. This Review provides a comprehensive overview of this field, including the early stoichiometric investigations, catalytic reaction developments, as well as the applications in the syntheses of bioactive compounds and polymers. The section of catalytic reactions is divided into two parts according to the reaction initiation mode: Pd(0)-initiated reactions and Pd(II)-initiated reactions.