New complexes of the hydronium ion with crown ethers: synthesis and vibrational spectra
New complexes of the hydronium ion with crown ethers: synthesis and vibrational spectra
复制标题
水合氢离子与冠醚的新配合物：合成和振动光谱
DOI：
10.1139/v84-390
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发表时间：
1984
影响因子：
1.1
通讯作者：
R. Savoie
中科院分区：
文献类型：
--
作者：
R. Chěnevert;A. Rodrigue;Pierre Beauchesne;R. Savoie
带电组分复合物 H3O+•18-crown-6.CF3SO3−、H3O+•18-crown-6.SbF6− 和 (H3O+•18-crown-6)2•PtCl62− 已通过红外和拉曼光谱分离和研究，以及先前报道的 H3O+•18-crown-6•C1O4− 和H3O+•18-冠-6•PF6− 加合物。还合成了相应的 BF4− 和 PtCl62− 阴离子衍生物，使用 dicyclohexano-18-crown-6 作为水合氢离子的主体。
The charged-component complexes H3O+•18-crown-6.CF3SO3−, H3O+•18-crown-6.SbF6−, and (H3O+•18-crown-6)2•PtCl62− have been isolated and studied by infrared and Raman spectroscopy, along with the previously reported H3O+•18-crown-6•C1O4− and H3O+•18-crown-6•PF6− adducts. Also synthesized were the corresponding derivatives with BF4− and PtCl62− anions, using dicyclohexano-18-crown-6 as the host for the hydronium ion.