THE MUKAIYAMA ALDOL AND MUKAIYAMA-MICHAEL REACTIONS PROMOTED BY COMMERCIALLY AVAILABLE MOLECULAR SIEVES
THE MUKAIYAMA ALDOL AND MUKAIYAMA-MICHAEL REACTIONS PROMOTED BY COMMERCIALLY AVAILABLE MOLECULAR SIEVES
复制标题
市售分子筛促进的向山醛醇反应和向山-迈克尔反应
DOI：
10.3987/com-09-s(s)133
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发表时间：
2010
期刊：
影响因子：
0.6
通讯作者：
Yudai Watanabe
中科院分区：
文献类型：
--
作者：
M. Anada;Takuya Washio;Yudai Watanabe
甲硅烷基烯酮缩醛与醛的Mukaiyama羟醛缩合反应已通过使用市售的4A分子筛（4A MS）作为促进剂进行。各种甲硅烷基烯酮缩醛和甲硅烷基烯醇醚已被证明是该反应的有效亲核试剂。首次发现4A MS对甲硅烷基烯酮缩酮与α，β-烯酮的Mukaiyama-Michael加成反应有促进作用。
The Mukaiyama aldol reaction of silyl ketene acetals with aldehydes has been effected by using commercially available 4A molecular sieves (4A MS) as a promoter. Various silyl ketene acetals and silyl enol ethers have been shown to be effective nucleophiles for this reaction. For the first time, it has been found that 4A MS can promote the Mukaiyama―Michael addition reactions of silyl ketene acetals to α,β-enones.
影响因子：
5.2
作者：
Amos B. Smith;Thomas M. Razler;J. Ciavarri;T. Hirose;T. Ishikawa
通讯作者：
Amos B. Smith;Thomas M. Razler;J. Ciavarri;T. Hirose;T. Ishikawa