Substitution of a platinum (II) complex without retention of stereochemistry; direct evidence for pseudorotation of a five-co-ordinate platinum (II) cationic complex containing chelating phosphine ligands
Substitution of a platinum (II) complex without retention of stereochemistry; direct evidence for pseudorotation of a five-co-ordinate platinum (II) cationic complex containing chelating phosphine ligands
复制标题
取代铂 (II) 络合物而不保留立体化学；
DOI：
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发表时间：
1981
期刊：
影响因子：
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通讯作者：
J. Downes
中科院分区：
文献类型：
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作者：
M. Cooper;J. Downes
反式-[Pt(PNH2)(PNH2)Cl]+(2)[PNH2=（o -氨基苯基）二苯基膦PNH2表示单齿配位通过磷]的过程而不保留立体化学；这是五坐标铂（II）配合物赝旋作用的第一个直接证据。
Ring closure of trans-[Pt(PNH2)(PNH2)Cl]+(2)[PNH2=(O-aminophenyl)diphenylphosphine; PNH2 denotes monodentate co-ordination through the phosphorus] proceeds without retention of stereochemistry; this is the first direct evidence for pseudorotation of five-co-ordinate platinum (II) complex.