Time-correlated Single Ion Counting Mass Spectrometer with Long and Short Time-of-Flight Tubes and an Evaluation of Its Performance for Use in Trace Analysis of Allergenic Substances

Time-correlated Single Ion Counting Mass Spectrometer with Long and Short Time-of-Flight Tubes and an Evaluation of Its Performance for Use in Trace Analysis of Allergenic Substances
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DOI:
10.2116/analsci.19sbp03
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发表时间:
2020-05-01
影响因子:
1.6
通讯作者:
Imasaka, Totaro
Imasaka, Totaro
中科院分区:
化学4区
文献类型:
--
作者:
Ju, Tiantian;Yoshinaga, Katsunori;Imasaka, Totaro

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用飞秒激光作为电离源电离被分析物分子,用长(42厘米)和短(6.4厘米)飞行管的双型飞行时间质谱仪进行测量。使用模拟信号数字化仪和时间相关单离子计数系统测量信号,并通过比较两种仪器获得的数据来评估性能。短质谱计的质量分辨率为450,可用于香精中致敏物质的痕量分析。
An analyte molecule was ionized using a femtosecond laser as the ionization source and was measured by a twin-type time-of-flight mass spectrometer with long (42 cm) and short (6.4 cm) flight tubes. The signal was measured using an analog signal digitizer and a time-correlated single ion counting system, and performance was evaluated by comparing data obtained from both instruments. The short mass spectrometer had a mass resolution of 450 and was used in the trace analysis of allergenic substances in a fragrance.