Gas-phase synthesis and reactivity of Cu+-benzyne complexes
Gas-phase synthesis and reactivity of Cu+-benzyne complexes
复制标题
苯炔铜配合物的气相合成及其反应活性
DOI：
10.1039/c4cc04168b
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发表时间：
2014-01-01
影响因子：
4.9
通讯作者：
Pan, Yuanjiang
中科院分区：
文献类型：
--
作者：
Chai, Yunfeng;Shen, Shanshan;Pan, Yuanjiang
首次在气相中合成了含双齿氮配体的Cu ~+-苯炔配合物。在离子阱分析仪上研究了铜稳定苯炔与胺的加成反应。通过比较其MSn数据与从另一种生成途径获得的真实化合物来鉴定产物的结构。
Cu+-benzyne complexes bearing bidentate nitrogen ligands were synthesized in the gas phase for the first time using electrospray ionization mass spectrometry. The addition reactivity of copper-stabilized benzyne with amines was studied in the ion trap analyzer. The structures of products were identified by comparing their MSn data with authentic compounds obtained from another generation route.