Major influence of hydroxyl and nitrate radicals on air pollution by environmentally persistent free radicals
Major influence of hydroxyl and nitrate radicals on air pollution by environmentally persistent free radicals
复制标题
羟基和硝酸根对环境持久性自由基造成的空气污染的主要影响
DOI：
10.1007/s10311-021-01278-9
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发表时间：
2021-07
影响因子：
15.7
通讯作者：
Zhang Aiqian
中科院分区：
文献类型：
--
作者：
Pan Wenxiao;Chang Jiamin;He Shuming;Xue Qiao;Liu Xian;Fu Jianjie;Zhang Aiqian
Environmentally persistent free radicals are pollutants recently detected in most environmental matrices such as fly ash, aerosols, soils and sediments. Their generation and transformation is poorly known, notably in the atmopshere. Here we modeled the effect of dioxygen O2, hydroxyl radical•OH, and nitrate radical NO3on Cu(II)O surface-bound phenoxyl radical, using quantum chemical calculations and kinetics analysis. Results show that additional stabilization of the surface-bound phenoxyl radical is provided by the metal-oxide surface, implying that self-decomposition is not likely to occur. The addition reactions of hydroxyl and nitrate radicals with surface-mediated radicals are both thermodynamically and kinetically favorable, whereas the role of O2appears negligible. The tropospheric lifetime of the Cu(II)O-based surface-bound phenoxyl radical is only few seconds to about one hour, in agreement with experimental observations from the literature.
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影响因子：
11.4
作者：
Vejerano, Eric;Lomnicki, Slawomir M.;Dellinger, Barry
通讯作者：
Dellinger, Barry
雾霾相关大气中环境持久性自由基的高浓度和粒径分布
影响因子：
11.4
作者：
Yang Lili;Liu Guorui;Zheng Minghui;Jin Rong;Zhu Qingqing;Zhao Yuyang;Wu Xiaolin;Xu Yang
通讯作者：
Xu Yang
影响因子：
11.4
作者：
Gehling W;Dellinger B
通讯作者：
Dellinger B
DOI：
10.1002/chin.201248241
发表时间：
2012-11
期刊：
ChemInform
影响因子：
--
作者：
S. Brown;J. Stutz
通讯作者：
S. Brown;J. Stutz
影响因子：
--
作者：
Liu, RF;Morokuma, L;Liu, MC
通讯作者：
Liu, MC