Ternary Nitrides, Phosphides, and Arsenides of Lithium
Ternary Nitrides, Phosphides, and Arsenides of Lithium
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锂的三元氮化物、磷化物和砷化物
DOI：
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发表时间：
1968
期刊：
影响因子：
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通讯作者：
K. Benda
中科院分区：
文献类型：
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作者：
R. Juza;K. Langer;K. Benda
三元相由锂、另一种金属和氮、磷或砷制备。三元化合物，特别是氮化物，比二元化合物热稳定。锂产生相对高极性的键合组分。在高温下，锂和第二金属通常随机分布在准金属晶格的间隙中。通过 X 射线和磁性方法以及差热分析研究了随着温度降低而发生的有序过程。这些阶段根据结构分为七组。
Ternary phases have been prepared from lithium, another metal, and nitrogen, phosphorus, or arsenic. The ternary compounds, in particular the nitrides, are thermally more stable than the binary compounds. The lithium gives rise to a relatively high polar bonding component. At high temperatures, lithium and the second metal are often randomly distributed among the interstices of the metalloid lattice. The ordering processes that take place with decreasing temperature are investigated by X-ray and magnetic methods and by differential thermal analysis. The phases are classified on a structural basis into seven groups.