A Selective Ru-Catalyzed Semireduction of Alkynes to Z Olefins under Transfer-Hydrogenation Conditions
A Selective Ru-Catalyzed Semireduction of Alkynes to Z Olefins under Transfer-Hydrogenation Conditions
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DOI：
10.1002/chem.201001143
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发表时间：
2010-01-01
影响因子：
4.3
通讯作者：
Plietker, Bernd
中科院分区：
文献类型：
--
作者：
Belger, Christian;Neisius, N. Matthias;Plietker, Bernd
通过使用易于获得的、空气和水分稳定的二氢-Ru络合物，可以在转移氢化条件下以甲酸作为氢源以优异的产率和Z/E选择性获得多种Z烯烃。
By using a readily available, air- and moisture-stable dihydrido-Ru complex, a variety of Z olefins are accessible under transfer-hydrogenation conditions with formic acid as the hydrogen source in excellent yields and Z/E selectivities.