A study of provenance and dating of ancient Chinese porcelain by x‐ray fluorescence spectrometry

A study of provenance and dating of ancient Chinese porcelain by x‐ray fluorescence spectrometry
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DOI:
10.1002/(sici)1097-4539(200001/02)29:1
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发表时间:
2000
期刊:
影响因子:
1.2
通讯作者:
P. L. Leung;Hongjie Luo
P. L. Leung;Hongjie Luo
中科院分区:
物理与天体物理4区
文献类型:
--
作者:
P. L. Leung;Hongjie Luo

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为了扩大用主量元素研究制造技术演变过程的范围,我们用有金属、次要和/或微量元素研究了来源和年代,并用能量色散X射线荧光(EDXRF)光谱鉴别了中国陶瓷器的真伪。在总结前人工作的基础上,对景德镇、德化、河北(兴、定、磁州)的85件典型中国白瓷器物进行了EDXRF测量,并进行了进一步的统计分析。对景德镇、德化、河北等地的样品,以及河北的邢县、丁县、磁州等地的样品,建立了判别函数。还推导了景德镇青花瓷元代、明代、清代样品和德化白瓷宋代至元明时期样品的测年函数。建议在所有判别函数中采用元素比值,以减小测量误差,形成一种快速、无损、可比、可靠的古瓷器来源和年代测定方法。版权所有©2000 John Wiley&Sons,Ltd.
In order to extend the scope of employing major elements to study the evolution process of manufacturing techniques, we employed loyed minor and/or trace elements to study provenance and dating and to distinguish fake from original Chinese pottery and porcelain by energy-dispersive x-ray fluorescence (EDXRF) spectrometry. In summarizing our previous work, 85 typical Chinese white porcelain objects from Jingdezhen, Dehua and Hebei (Xing, Ding and Cizou), were measured by EDXRF and further analysed statistically. We found discriminate functions for the provenance of samples among Jingdezhen, Dehua and Hebei and also samples among Xing, Ding and Cizou in Hebei. We also derived functions for dating samples among Yuan, Ming and Qing of Jingdezhen blue and white porcelain, and samples between Song to Yuan and Ming periods of Dehua white porcelain. Element ratios are suggested to be employed in all of the discriminate functions in order to minimize measurement errors and to form a fast, non-destructive, comparable and reliable method for provenance and dating of ancient porcelain. Copyright © 2000 John Wiley & Sons, Ltd.