On the lower excited electronic states of decacyclene
On the lower excited electronic states of decacyclene
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关于十环烯的低激发电子态
DOI：
10.1063/1.1679678
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发表时间：
1973
影响因子：
4.4
通讯作者：
G. J. Hoijtink
中科院分区：
文献类型：
--
作者：
C. Brugman;P. J. V. Scherpenzeel;R. Rettschnick;G. J. Hoijtink
给出了十环烯的吸收光谱和发射光谱。实验数据进行了比较的Pariser-Parr型的配置相互作用计算的结果，包括双激发配置。对于低激发态，实验和计算的项方案之间的一致性是令人满意的。可以证明，S 0-S1跃迁是对称禁戒的。
Absorption and emission spectra of decacyclene are presented. The experimental data are compared with the results of configuration interaction calculations of the Pariser‐Parr type including doubly excited configurations. The agreement between the experimental and the calculated term schemes is satisfactory for the lower excited states. It can be shown that the S0‐S1 transition is symmetry forbidden.