Recent Advances in the Nanocatalyst-Assisted NaBH4 Reduction of Nitroaromatics in Water
Recent Advances in the Nanocatalyst-Assisted NaBH4 Reduction of Nitroaromatics in Water
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DOI：
10.1021/acsomega.8b03051
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发表时间：
2019-01
期刊：
影响因子：
4.1
通讯作者：
Kaiqiang Zhang;J. Suh;Ji-won Choi;Ho Won Jang;M. Shokouhimehr;R. Varma
中科院分区：
文献类型：
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作者：
Kaiqiang Zhang;J. Suh;Ji-won Choi;Ho Won Jang;M. Shokouhimehr;R. Varma
鉴于纳米催化在化学转化中越来越多的应用，本文阐述了纳米催化剂用于重要还原反应的最新进展，即用NaBH 4水溶液将硝基芳烃加氢为重要的氨基芳烃;包括单金属和多金属纳米催化剂的效用，特别强调非均相纳米催化剂。纳米催化剂的适用性的进步趋势也纳入了大规模的应用和他们的可持续的结晶化和再利用利用支持和磁性纳米催化剂;合成这种可重复使用的纳米催化剂的代表性方法的特点。
In view of the increasing applications of nanocatalysis in chemical transformations, this article illustrates recent advances on the use of nanocatalysts for an important reduction reaction, the hydrogenation of nitroaromatics to significant aminoaromatics with aqueous NaBH4 solution; the utility of mono- and multimetal nanocatalysts with special emphasis on heterogeneous nanocatalysts is included. A progressive trend on the applicability of nanocatalysts is also incorporated with large-scale application and their sustainable recyclization and reuse utilizing supported and magnetic nanocatalysts; representative methods for the synthesis of such reusable nanocatalysts are featured.