Preparation of zinc-homoenolate from α-sulfonyloxy ketone and bis(iodozincio)methane
Preparation of zinc-homoenolate from α-sulfonyloxy ketone and bis(iodozincio)methane
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DOI：
10.1246/cl.2007.164
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发表时间：
2007-01-05
影响因子：
1.6
通讯作者：
Matsubara, Seijiro
中科院分区：
文献类型：
--
作者：
Nomura, Kenichi;Matsubara, Seijiro
α-磺酰氧基酮与双(碘并)-甲烷反应得到环丙氧锌，该试剂通过亲核加成到羰基上，然后进行分子内取代反应。
Treatment of alpha-sulfonyloxy ketone with bis(iodozincio)-methane gives a zinc cyclopropoxide which is formed via a nucleophilic addition of the reagent to carbonyl group followed by an intramolecular substitution reaction.