Ba2B10O16(OH)2·(H3BO3)(H2O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate.
Ba2B10O16(OH)2·(H3BO3)(H2O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate.
复制标题
DOI：
10.1021/acs.inorgchem.2c00102
复制
发表时间：
2022-03
影响因子：
4.6
通讯作者：
Wen-Zhuo Zhao;Yi-Nan Zhang;Y. Lan;Jian-Wen Cheng;Guo‐Yu Yang
中科院分区：
文献类型：
--
作者：
Wen-Zhuo Zhao;Yi-Nan Zhang;Y. Lan;Jian-Wen Cheng;Guo‐Yu Yang
用水热法合成了一种新的偏心硼酸钡Ba2B10O16(OH)2·(H3BO3)(H2O)(1)。化合物1含有两个不同的氧化硼单元[B5O10(OH)]6-阴离子和H3BO3分子，并具有沿c轴呈层状结构的9环通道。该晶体具有中等的二次谐波信号和190 nm以下宽的透明窗口，是一种可能的深紫外非线性光学晶体。
A new acentric barium borate, Ba2B10O16(OH)2·(H3BO3)(H2O) (1), was synthesized via a hydrothermal process. Compound 1 contains two different boron oxide units of [B5O10(OH)]6- anions and H3BO3 molecules and features 9-ring channels along the c axis in a layered structure. This barium borate is a possible deep-ultraviolet nonlinear-optical crystal for its moderate second-harmonic-generation signal and wide transparency window below 190 nm.