Synthesis, Characterization, and Utilization of a Novel Phosphorus/Nitrogen-Containing Flame Retardant
Synthesis, Characterization, and Utilization of a Novel Phosphorus/Nitrogen-Containing Flame Retardant
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新型磷/氮阻燃剂的合成、表征及应用
DOI：
10.1021/ie505021d
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发表时间：
2015-03-25
影响因子：
4.2
通讯作者：
Hu, Zhongwu
中科院分区：
文献类型：
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作者：
Jiang, Peng;Gu, Xiaoyu;Hu, Zhongwu
采用经典的Atherton-Todd反应合成了含有磷腈[9,10-二氢-9-氧杂-10-磷腈10-氧化物（DOPO）]和磷腈（六氯环三磷腈）基团的新型磷/氮阻燃剂六（磷杂菲氨基苯氧基）环三磷腈（HPAPC），并通过傅里叶变换红外表征了其化学结构。 （FTIR）和核磁共振（NMR）光谱。采用熔融共混法制备了含有 HPAPC 的聚乳酸（PLA）复合材料，并通过极限氧指数（LOI）、垂直燃烧（UL-94）、锥形量热仪测试和热重分析（TGA）研究了其防火性能和热行为。仅含有 5 wt% HPAPC 的 PLA 复合材料的 LOI 值可达 34.7%，且 UL-94 可以通过 V-0。 TGA 结果表明，HPAPC 的存在可以显着改善 PLA 的成炭作用。通过 F 分析复合材料的逸出气体...
The novel phosphorus/nitrogen-containing flame retardant hexa(phosphaphenanthrene aminophenoxyl)cyclotriphosphazene (HPAPC), which contains phosphaphenanthrene [9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO)] and phosphazene (hexachlorocyclotriphosphazene) groups, was synthesized by the classic Atherton–Todd reaction, and its chemical structure was characterized by Fourier transform infrared (FTIR) and nuclear magnetic resonance (NMR) spectroscopies. Poly(lactic acid) (PLA) composites containing HPAPC were prepared by melt blending, and their fire performance and thermal behaviors were investigated in terms of limiting oxygen index (LOI), vertical burning (UL-94), cone calorimeter tests, and thermogravimetric analysis (TGA). The LOI value could reach up to 34.7%, and UL-94 could pass V-0 for the PLA composite containing only 5 wt % HPAPC. TGA results showed that the char formation of PLA could be significantly improved by the presence of HPAPC. The evolved gas of the composite was analyzed by F...