Enhancing the hydrodesulfurization of 4,6-dimethyldibenzothiophene through the use of mixed MoWS2 phase evidenced by HAADF
Enhancing the hydrodesulfurization of 4,6-dimethyldibenzothiophene through the use of mixed MoWS2 phase evidenced by HAADF
复制标题
HAADF 证明通过使用混合 MoWS2 相增强 4,6-二甲基二苯并噻吩的加氢脱硫
DOI:
10.1016/j.cattod.2018.11.051
复制
发表时间:
2019
期刊:
影响因子:
5.3
通讯作者:
P. A. Nikul’shin
中科院分区:
文献类型:
--
作者:
M. Nikul’shina;A. Mozhaev;C. Lancelot;P. Blanchard;M. Marinova;C. Lamonier;P. A. Nikul’shin
HighlightsMoW/Al 2 O 3 catalysts were prepared using H 4 SiMo n W 12-n O 40 heteropolyacids (HPA).W sulfidation degree increases with Mo loading.Mo 3 W 9/Al 2 O 3 has the highest activity in HDS of DBT, 4, 6-DMDBT and naphthalene HYD.MoW HPAs based catalysts has the highest S HYD/DDS in DBT as well as 4, 6-DMDBT HDS.Gas phase activation is more preferable for activity of MoW catalysts than liquid phase.