STEREOCHEMICAL AND VIBRATIONAL THEORIES OF ODOUR

STEREOCHEMICAL AND VIBRATIONAL THEORIES OF ODOUR
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DOI:
10.1038/233270a0
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发表时间:
1971-01-01
期刊:
影响因子:
64.8
通讯作者:
AMOORE, JE
AMOORE, JE
中科院分区:
综合性期刊1区
文献类型:
--
作者:
AMOORE, JE

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尽管已经提出了许多关于气味特异性的理论,但只有两种理论得到了定量测量和统计分析的支持。我的立体化学理论将各种化合物的气味与其分子模型的大小和形状联系起来。赖特的振动理论将气味与远红外光谱中的某些吸收峰联系起来。直接比较我们两个理论的相对成功是很有趣的,但到目前为止还不可能,因为我们使用了不同的测试化合物和不同的统计标准。
ALTHOUGH many theories of odour specificity have been proposed, only two have been supported by quantitative measurements with statistical analysis. My Stereochemical theory correlates the odours of various compounds with the sizes and shapes of their molecular models1. Wright's vibrational theory relates the odours to certain absorption peaks in their far infrared spectra2. It would be interesting to compare the relative success of our two theories directly, but so far this has not been possible, because we had used different test compounds and different statistical criteria.