OCCURRENCE OF INDOLE ALKALOIDS IN AILANTHUS-ALTISSIMA CELL-CULTURES
OCCURRENCE OF INDOLE ALKALOIDS IN AILANTHUS-ALTISSIMA CELL-CULTURES
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DOI：
10.1021/np50048a007
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发表时间：
1986-11-01
影响因子：
5.1
通讯作者：
MINGHETTI, A
中科院分区：
文献类型：
--
作者：
CRESPIPERELLINO, N;GUICCIARDI, A;MINGHETTI, A
用角叉菜-6-酮和β-羟基喹啉制备生物碱报道了臭椿细胞培养物的咔啉结构。除了canthin-6-酮（1）、1-甲氧基canthin-6-酮（2）、canthin-6-酮-3-氧化物（7）、1-甲氧基canthin-6-酮-3-氧化物（8）、1-羟基canthin-6-酮（3）、5-羟基canthin-6-酮（6）、β-咔啉-1-丙酸（11）和4-甲氧基-β-咔啉-1-羧酸甲酯（10）是三种新生物碱。它们是2-羟基canthin-6-酮（4）、4-羟基canthin-6-酮（5）和4，5-二氢canthin-6-酮（9）。
Production of alkaloids with both canthin-6-one and .beta.-carboline structure by Ailanthus altissima cell cultures is reported. Besides canthin-6-one(1), 1-methoxycanthin-6-one (2), canthin-6-one-3-oxide (7), 1-methoxycanthin-6-one-3-oxide (8), 1-hydroxycanthin-6-one (3), 5-hydroxycanthin-6-one (6), .beta.-carboline-1-propionic-acid (11), and 4-methoxy-.beta.-carboline-1-carboxylic acid methylester (10), three new alkaloids are described. These are 2-hydroxycanthin-6-one (4), 4-hydroxycanthin-6-one (5), and 4,5-dihydrocanthin-6-one (9).