Types of cationic complexes based on oxocentred tetrahedra [OM4] in the crystal structures of inorganic compounds

Types of cationic complexes based on oxocentred tetrahedra [OM4] in the crystal structures of inorganic compounds
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无机化合物晶体结构中基于氧中心四面体[OM4]的阳离子配合物类型

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发表时间:
1998
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通讯作者:
T. F. Semenova
T. F. Semenova
中科院分区:
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文献类型:
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作者:
S. V. Krivovichev;S. Filatov;T. F. Semenova

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无机化合物的晶体结构,包括阳离子配合物含有氧原子配位四面体的金属原子,或oxocentred基团[OM 4],被认为是。分析了[OM 4]四面体在结构中的连接,并鉴定了不同结构的阳离子配合物。[OM 4]四面体的连接规则已制定和阳离子配合物已进行了详细的系统的治疗在其基础上。的[OM 4]四面体的键长和键角的统计数据。参考文献包括317篇参考文献。
The crystal structures of inorganic compounds comprising cationic complexes containing oxygen atoms coordinated tetrahedrally to metal atoms, or oxocentred groups [OM4], are considered. The linking of the [OM4] tetrahedra in the structures has been analysed and cationic complexes of different structures have been identified. The rules governing the linking of the [OM4] tetrahedra have been formulated and the cationic complexes have been subjected to a detailed systematic treatment on their basis. Data on the statistics of the bond lengths and bond angles in the [OM4] tetrahedra are presented. The bibliography includes 317 references.