Competition between carbon-oxygen and 1-carbon-hydrogen bond scission during deoxygenation: the reactions of 1-propanol on molybdenum(110)
Competition between carbon-oxygen and 1-carbon-hydrogen bond scission during deoxygenation: the reactions of 1-propanol on molybdenum(110)
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脱氧过程中碳-氧和1-碳-氢键断裂的竞争：1-丙醇在钼上的反应(110)
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发表时间：
1992
期刊：
影响因子：
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通讯作者：
C. Friend
中科院分区：
文献类型：
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作者：
B. Wiegand;P. Uvdal;J. Serafin;C. Friend
用程序升温反应、高分辨电子能量损失和X射线光电子能谱研究了正丙醇在Mo(110)面上的反应。120K时，1-丙醇吸附在Mo(110)面上生成1-丙氧基。振动数据的强度分析表明，C-O键矢几乎垂直于表面。振动数据还表明，与1-丙醇相比，1-丙氧基中的C-O键减弱
The reactions of 1-propanol on Mo(110) were investigated using temperature programmed reaction and high resolution electron energy loss and X-ray photoelectron spectroscopies. 1-Propanol forms 1-propoxide upon adsorption on Mo(110) at 120 K. An intensity analysis of the vibrational data indicates that the C-O bond vector is nearly perpendicular to the surface. Vibrational data also suggest that the C-O bond is weakened in 1-propoxide relative to 1-propanol