Control of cycloreversion quantum yields of diarylethenes by introduction of substituents at the reactive carbons

Control of cycloreversion quantum yields of diarylethenes by introduction of substituents at the reactive carbons
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DOI:
10.1080/15421400590947072
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发表时间:
2005-01-01
影响因子:
0.7
通讯作者:
Irie, M
Irie, M
中科院分区:
化学4区
文献类型:
--
作者:
Morimitsu, K;Kobatake, S;Irie, M

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合成了几种活性碳上具有不同取代基的二芳基乙烯衍生物,并测量了它们的量子产率。虽然取代基的引入对环化反应的量子产率影响不大,但环化反应的量子产率随取代基的不同而不同。
Several diarylethene derivatives having various substituents at the reactive carbons were prepared and the quantum yields were measured. Although the cyclization quantum yields were scarcely affected by the introduction of substituents, the cycloreversion quantum yields varied depending on the substituents.