An all-solid-state rechargeable aluminum-air battery with a hydroxide ion-conducting Sb(V)-doped SnP2O7 electrolyte
An all-solid-state rechargeable aluminum-air battery with a hydroxide ion-conducting Sb(V)-doped SnP2O7 electrolyte
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DOI：
10.1039/c3ta12707a
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发表时间：
2013-01-01
影响因子：
11.9
通讯作者：
Nagao, Masahiro
中科院分区：
文献类型：
--
作者：
Hibino, Takashi;Kobayashi, Kazuyo;Nagao, Masahiro
无水氢氧化物离子导体Sn0.92Sb0.08P2O7可用作铝-空气电池的电解液，在放电过程中铝被氧化成铝酸盐物种，铝酸盐物种通过充电被还原为铝。该电池的开路电压约为1.6V，放电容量约为800 mA h g(1)电极。
An anhydrous hydroxide ion conductor, Sn0.92Sb0.08P2O7, can function as an electrolyte for aluminum-air batteries, where aluminum is oxidized to an aluminate species during discharge, and the aluminate species is reduced to aluminum by charging the cell. This battery generated an open-circuit voltage of ca. 1.6 V with a discharge capacity of ca. 800 mA h g (1) electrode.