Synthesis of some unsymmetrical bridged terpyridines

Synthesis of some unsymmetrical bridged terpyridines
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DOI:
10.1021/jo016250v
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发表时间:
2002-04-05
影响因子:
3.6
通讯作者:
Lebedev, RL
Lebedev, RL
中科院分区:
化学2区
文献类型:
--
作者:
Kelly, TR;Lebedev, RL

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使用分子内和分子间迈克尔加成作为关键反应,然后构建中心吡啶环,合成了新型不对称三联吡啶1和2。三联吡啶1代表迄今未知​​的六环系统。
Novel unsymmetrical terpyridines 1 and 2 are synthesized using intra- and intermolecular Michael additions as the key reactions, followed by the construction of the central pyridine ring. Terpyridine 1 represents a heretofore unknown hexacyclic ring system.