Polymer-Supported Ruthenium Porphyrins: Versatile and Robust Epoxidation Catalysts with Unusual Selectivity
Polymer-Supported Ruthenium Porphyrins: Versatile and Robust Epoxidation Catalysts with Unusual Selectivity
复制标题
DOI：
10.1021/ja000461k
复制
发表时间：
2000-05
影响因子：
15
通讯作者：
Xiao-Qi Yu;Jie‐Sheng Huang;Wing-Yiu Yu;C. Che
中科院分区：
文献类型：
--
作者：
Xiao-Qi Yu;Jie‐Sheng Huang;Wing-Yiu Yu;C. Che
制备了5，10，15-三（4-R-苯基）-20-（4-羟基苯基）卟啉（R = Cl，Me）羰基钌（II）与梅里菲尔德肽树脂的共价连接。结果表明，R = Cl的催化剂具有较好的催化活性。
Carbonyl ruthenium(II) 5,10,15-tris(4-R-phenyl)-20-(4-hydroxyphenyl)porphyrins (R = Cl, Me) covalently attached to Merrifield's peptide resin were prepared. The catalyst with R = Cl was found to ef...